Structural and Luminescence Properties in Dy3+ Doped Antimony Strontium-Magnesium-Oxyfluroborate Glasses
DOI:
https://doi.org/10.48165/Keywords:
Oxyfluoroborate glasses, optical, XRD, UV-NIR, Radioactive PropertiesAbstract
A series of glasses by melting quenching method fabricated for spectroscopic investigations of Dysprosium (Dy3+) particle ions deposited on Antimony (Sb) - Magnesium (Mg) - Strontium (Sr) Oxyfluoroborate (BSbMgfSr) glasses. The structural and optical characterizations such as XRD, UV-VIS-NIR absorption spectroscopy, photoluminescence (PL) (excitation and emission) were accomplished to study the properties of prepared glasses. The transitions from lowest energy state to an excited state in RE3+ ions were identified using optical UV-NIR absorption spectra. By the use of Judd-Ofelt theory the J-O intensity parameters Ωλ (λ = 2, 4, 6) have been evaluated utilizing the absorption spectra with the determination of experimental (fexp) and calculated (fcal) oscillator strengths. The emission of light from glass system was concluded through PL spectra (Excitation and emission) for Dy3+ion. The radiative properties resembling radiative transition probability (AR), radiative-lifetime (τR), and branching-ratio (β) of the glasses have also estimated. Stimulated emission cross-section (σse) of the glasses also calculated for the feasibility of lasing applications. Experimental lifetime (τexp) of the decay curves of the BSbMgfSrD glasses were also calculated upon excitation by suitable wavelengths of all various concentrations of the RE3+ ions.
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