Langmuir–Hinshelwood kinetic expression and kinetic studies of photo catalytic degradation of copper surfactants derived from edible oils by semiconductor Zinc Oxide
DOI:
https://doi.org/10.48165/Keywords:
Zinc oxide, Photo catalytic degradation, Semiconductor, Copper mustard and soyabean surfactantsAbstract
The copper mustard and soyabean surfactants have been synthesize and characterize by IR and NMR spectroscopic techniques. The photo catalytic degradation of copper mustard and soyabean surfactants have been carried out by zinc oxide in non- aqueous solutions. Various factors such as effect of concentration, dose of ZnO, light intensity and solvent polarity were varied to achieve the optimum rate of photo degradation. Both copper surfactants were degraded successfully by using ZnO under UV light. The disappearance of copper surfactants follows a pseudo-first- order kinetics according to the Langmuir–Hinshelwood (L–H) model.
Downloads
References
Khan, S., Sharma, R., Sharma, A.K.: Acoustic studies and other Acoustic Parameters of Cu(II) Soap derived from nonedible Neem oil (Azadirectaindica), in Non-aqueous media at 298.15, Acta Ac united Ac. 104 (2018) 277-283; http://DOI10.3813/AAA.919170.
Sharma, A.K., Saxena, M., and Sharma, R.: Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils, Tenside. Surf. Det. 55(2), (2018) 127-134. https://doi.org/10.3139/113.110544
Tank, P., Sharma R., Sharma, A. K.: A Pharmaceutical approach & Antifungal activities of Copper Soaps with their N & S donor complexes derived from Mustard and Soyabean oils, Glob. J Pharmaceu. Sci. 3(4) (2017) GJPPS.MS.ID.555619; https://doi.org/10.19080/GJPPS.2017.03.555619
Rashmi S, Arun K S.: Natural Edible Oils: Comparative Health Aspects Of Sesame, Coconut, Mustard (Rape Seed) and Groundnut (Peanut) A Biomedical Approach, Biomed.J.Sci.&Tech.Res.1(5)(2017)
BJSTR.MS.ID.000441;https://doi.org/10.26717/BJSTR.2017.01.000441
Tank, P., Sharma, R. and Sharma, A.K.: Viscometric Studies of Cu (II) surfactants derived from mustard oil in benzene at 303.15K, Tenside Surf. Det. (2018) (Accepted)
Sharma, A.K., Sharma, R. Saxena, M.: Biomedical and antifungal application of Cu(II) soaps and its urea complexes derived from various oils, Open access J Trans Med res 2(2) (2018) 40-43; https://Doi:10.15406/oajtmr.2018.02.00033
Tank, P., Sharma, A.K., Sharma, R.: Thermal Behaviour and Kinetics of Copper (II) Soaps and Complexes Derived from Mustard and Soyabean Oil, J. Anal. Pharm. Res. 4(2) (2017) 1- 5;https://doi.org/10.15406/japlr.2017.04.00102
Sharma, S., Sharma, R., Sharma, A.K.: Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem, Asian J. Green Chem. 2(2) (2017) 129- 140;https://doi.org/10.22631/ajgc.2017.95559.1015
Sharma A.K., Sharma R., Gangwal A.: Biomedical and fungicidal application of copper surfactants derived from pure fatty acid, Organic & Medicinal Chem. IJ 5(5): (2018) 1-4; http://DOI:10.19080/OMCIJ.2018.05.555680
Joram, A., Sharma, R. and Sharma, A.K.: Thermal degradation of complexes derived from Cu (II) groundnut soap (Arachishypogaea) and Cu (II) sesame soap (Sesamumindicum), Z phys.Chem. 232(4) 459–470; https://doi.org/10.1515/zpch-2017-1073
Tank, P., Sharma, R., Sharma, A. K.: Micellar Features and Various Interactions of Copper Soap Complexes Derived from Edible Mustard Oil in Benzene at 303.15 K. Curr. Phy. Chem. 8(1) (2018) 46-57; http://DOI10.2174/1877946808666180102152443
Sharma, A.K., Sharma, R., Gangwal, A.: Antifungal activities and characterization of some new environmentally safe Cu (II) surfactants substituted 2-amino-6-methyl benzothiazole. Open Phar Sci. J. 5 (2018) 1-11; https://DOI:10.2174/187484490180501
Maensiri S., Laoki P. and Promarak V.: Synthesis and Optical Properties of Nanocrystalline ZnO Powders by a Simple Method Using Zinc Acetate Dehydrate and Poly (Vinyl Pyrrolidine). J. Cryst. Growth. 289 (2006) 102-106; http://dx.doi.org/10.1016/j.jcrysgro.2005.10.145
Bhatta, K.D., Sawant, D.N., Pinjari, D.V. Pandit, A.V. and Bhange B.M.: One Pot Green Synthesis of Nanosized Zinc Oxide by Sonochemical Method. Mater.Lett. 77, (2012) 93-95, http://dx.doi.org/10.1016/j.matlet.2012.03.012
Ameta, R., Punjabi, P.B. and Ameta, S.C.: Photodegradation of Naphthol Green B in Presence of Semiconducting Antimony Trisulphide. J. Serb. Chem. Soc. 7 (2011) 1049-1055; http://dx.doi.org/10.2298/JSC100425082A
Fabiyi, M.E., and Skelton, R.L.: Photocatalytic Mineralization of Methylene Blue Using Buoyant TiO2-CoatedPolystyrene Beads. J. Photochem. Photobiol. 132A (2000) 121-128; http://dx.doi.org/10.1016/S1010-6030(99)00250-
Subramonian. W., Wu, T.Y. Effect of enhancers and inhibitors on photocatalytic sunlight treatment of methylene blue. Water, Air, and Soil Pollution. 225 (2014) 1-15; http://DOI:10.1007/s11270-014-1922-0
Hachem, C., Bocquillon, F., Zahraa, O. and Bouchy M.: Decolourisation of Textile Industry Wastewater by the Photocatalytic Degradation Process. Dyes.Pigm. 49 (2001) 117-125, http://dx.doi.org/10.1016/S0143-7208(01)00014-6
Benjamin, S., Vaya, D., Punjabi, P.B. and Ameta, S.C.: Enhancing Photocatalytic Activity of Zinc Oxide by Coating with Some Natural Pigments. Arab. J. Chem., 4 (2011), 205-209.
http://dx.doi.org/10.1016/j.arabjc.2010.06.038
Soni, H., Kumar, N.J.I, Patel, K., Kumar, R. N.: Photo catalytic efficiency and kinetic studies of ZnO nanoparticles for the removal of basic dye Rhodamine B, Desalin. Water Treat. 57:42 (2016) 19857-19864; http://dx.doi.org/10.1080/19443994.2015.1102091
Soni, H., Kumar, N.J.I, Patel, K., Kumar, R. N.: Photocatalytic decoloration of three commercial dyes in aqueous phase and industrial effluents using TiO2 nanoparticles, Desalin. Water Treat. 57:14 (2016) 6355-6364; http://dx.doi.org/10.1080/19443994.2015.1005147
Jain, R., Sikarwar, S., Goyal, S.: Kinetics and isotherm studies on the adsorption of an antiparkinsonism drug Entacapone from aqueous solutions using unsaturated polyester resin (UPR), Desalin. Water Treat. 54 (2015) 3169-3176; http://dx.doi.org/10.1080/19443994.2014.910140
Jain, R., Sikarwar, S., Goyal, S.: Adsorption study of tetracycline onto an unsaturated polyester resin, Desalin. Water Treat. 57 (2016) 6875-6883; http://dx.doi.org/10.1080/19443994.2015.1013505
Bhutra, R., Sharma, R., Sharma, A.K: Volumetric studies of copper soap derived from treated and untreated oils in benzene at 298.15 K. Bulletin of Pure and Applied Sciences Section-C Chemistry. 37(2) (2018) 33-44; https://DOI10.5958/2320-320X.2018.00028.6
Sharma, A.K., Khan, S., Sharma, R.: Viscometric Behaviour and Micellar Studies of Cu (II) surfactant derived from Neem (AzadirectaIndica)) oil in methanol-benzene mixture at 298.15 K. Global Journal of Engineering Science and Researches. 5 (2018) 9 1;.https://DOI:10.5281/zenodo.1288395
Sharma, A. K. Saxena, M. Sharma R.: Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes, Bulletin of Pure and Applied Sciences. 36(2) (2017) 26-37; https://DOI10.5958/2320-320X.2017.00004.8
Sharma, S., Sharma, R., and Sharma, A.K.: Photo-degradation of Cu Soaps derived from Edible & Non Edible Oils“ISBN978-3-659-45043-3” LAP Lambert Academic Publishing Germany. (2017).
Sharma, S., Sharma, R., and Sharma, A.K.: Photo degradation of surfactants Towards Pollution free Society and Environment “ISBN978-93-86841-57-5”chapter published in book entitled Eco-tourism Environmental problems and sustainable development .
Sharma, R., Heda, L.C., and Sharma, S.: Photocatalytic Degradation of Copper (II) Palmitates in Non Aqueous Media Using ZnO as Photocatalyst, Tenside Surf. Det. 52 (2015) 512-516; http://DOI:10.3139/113.110404
Sharma, S., Sharma, R., Heda, L.C., and Sharma, A.K.: Kinetic parameters and Photo Degradation studies of Copper Soap derived from Soybean Oil using ZnO as a Photo catalyst in Solid and Solution Phase. J. Inst. Chemists (India). 89 (4) (2017) 119-136.
P. Tank, R. Sharma, A.K. Sharma, A.K., Viscometric Studies of Cu (II) surfactants derived from mustard oil in benzene at 303.15K, Tenside Surf Det. 2019, 56(2), 158-163 32. P. Kumawat, R. Sharma and Sharma A.K. Spectral, antimicrobial, TGA and photocatalytic degradation studies of copper neem–urea complex using synthetic, nano and doped ZnO, Int. J Environ An. Ch. 2019 (In Press).
N. Mathur, B. Manna, and A.K. Sharma, Kinetics and thermodynamics of thermal degradation and antimicrobial activity of zinc phenothiazine oleate complex, Bulletin of Pure and Applied Sciences 2019, 36(2), 13-26.
S. Khan, R. Sharma and A.K. Sharma, Volumetric and viscometric studies of copper surfactant derived from Karanj (Pongamia pinnata) oil in methanol-benzene mixture at 298.15 K.J of Phy. Sciences 2019, 50(2) 51-68.
S. Sharma, R. Sharma, S. Goyal S. and A.K. Sharma, Langmuir–Hinshelwood (L– H) adsorption isotherm and photo degradation of copper surfactants derived from saturated fatty acid catalyzed by zinc oxide, Indian Chem. Soc. 2019, 96, 281-288.