CMC and solute – solvent interactions of copper surfactants derived from fried oils in benzene at 298.15 K
DOI:
https://doi.org/10.48165/Keywords:
Copper, Surfactant-solvent interaction, CMC, Density, Apparent molar volumeAbstract
The density, M.V., and A.M.V. of copper surfactant derived from fried and unfried sesame and soyabean oils in non-aqueous and non- polar solvent benzene has been determined at constant temperature 298.15 K. Three samples of each oil were taken fresh, after treating at high temperature for 15 minutes and 60 minutes. The results were used to determine to CMC, chain length effect of the surfactant molecule on CMC and solute-solvent interactions. The studies were used to analyze the effect of high temperature treatment on the structure of the oil and molecular changes. The conclusions have been discussed in terms of well-known Masson’s. This helps us to the use of the oils after abuse of frying at high temperature as they have various industrial and biological applications. Colloidal behavior of copper surfactant used in to study of micellar features and their possible uses in agriculture and industries.
Downloads
References
S. Khan, R. Sharma, A.K. Sharma, Ultrasonic studies of Cu (II) Soap derived from seed oil of Pongamiapinnata (Karanj), in non-aqueous binary and ternary systems at 298.15K. Malasian J. Chem., 2017, 19(2), 99-110
A.K. Sharma,M. Saxena, R. Sharma, Acoustic Studies of Copper Soap- Urea complexes derived from Groundnut and Seasam oils. J. Phy. Studies.2017, 21(4)4601-6.
V.P. Mehta, P.R. telesara, R. Sharma, Molar volume and apparent molar volume of copper (II) soap+methanol+benzene system at various temperatures, Ind J chem., 2001, 39, 383-387. 4. A.K. Sharma,M. Saxena, R. Sharma, Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils. Tenside. Surf. Det., 2018, 55(2), 127-134.
M.R.K. Sherwani, R. Sharma, R. Bhutra, Micellar behaviour and solute-solvent interactions of copper soaps derived from fried vegetables oils in non-aqueous solvent, Int. J. Chem. Sci. 2008, 6(2), 735-745.
S. Khan, R. Sharma, A.K. Sharma, Acoustic studies and other Acoustic Parameters of Cu (II) Soap derived from non- edible Neem oil (Azadirectaindica), in Non-aqueous media at 298.15 Acta. Ac united Ac, 2018,104, 277-283.
N. Mathur, S. Bargotya, R. Mathur, Viscometric Behaviour and Miceller Studies of Some Biodegradable Organometallic Complexes in Binary Solvent System, Res. J. Pharm., Biol. Chem. Sci. 2014, 5(2), 989-997.
A. K. Sharma, R. Sharma, A. Gangwal, Biomedical and fungicidal application of copper surfactants derived from pure fatty acid, Org.& Med. Chem. 2018, IJ 5(5) 1-4
K.N. Mehrotra and M. Anis, Apparent molar volume and viscosity of zirconyl soaps, Colloids Surf A Physicochem Eng Asp., 1997, 122, 27-32.
Tank, P., Sharma R., Sharma, A. K. A Pharmaceutical approach & Antifungal activities of Copper Soaps with their N & S donor complexes derived from Mustard and Soyabean oils. Glob. J Pharmaceu. Sci., 2017, 3(4)1-6.
K. N. Mehrotra, V.P. Mehta, T.N. Nagar, Determination of Critical Micelle Concentration of copper soaps in nonaqueous solvents, J prakt. Chem., 1970, 312, 545-553.
A.K. Sharma, M. Saxena, R. Sharma, Synthesis, Spectroscopic and Biocidal activities of environmentally safe Agrochemicals. J Biochem. tech.2018, 7(3) 1139-1147.
S. Khan, R. Sharma, A.K. Sharma, Antifungal Activities of Copper Surfactants derived from Neem (AzadirectaIndica) and Karanj (Pongamia pinnata) Oils: A Pharmaceutical Application,Glob. J. Pharmaceu. Sci., 2017, 3(4), 1-6.
S. Sharma, R. Sharma, A.K. Sharma, Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem. Asian J. Green Chem., 2017, 2(2), 129-140.
K.N. Mehrotra, R.K. Shukla, M. Chauhan, Micellar behavior of neodymium soaps in methanol, J Appl. Polym. Sci., 1990, 39, 1745-1754.
A.K. Sharma, S. Sharma, R. Sharma, Thermal degradation of Cu (II) metallic Soaps and their Characterizations. A Pharmaceutical Application, Chro. Pharma Sci. 2017, 1(5), 312-319. 17. A. K. Sharma, R. Sharma, M. Saxena, Biomedical and antifungal application of Cu (II) soaps and its urea complexes derived from various oils. Open access J Trans Med res 2018, 2(2) 40-43. 18. D.O. Masson, Solute molecular volumes in relation to solvation and ionization, Philos. Mag., 1929, 8, 218-235.
K. N. Mehrotra, M. Jain, Viscometric and Ultrasonic Studies on Chromium Soap Solutions, J. Chem. Eng. Data, 1995, 40 (1), 91–95.
R. Bhutra, R. Sharma and A.K. Sharma, Comparative Studies of Fried & Unfried Oils as Cu (II) Surfactants“ISBN978-3-659-83122-5” LAP Lambert Academic Publishing, Germany, 2017. 21. K.N. Mehrotra M. Sharma and A. S. Gahlaut, Micellar behavior of praseodymium valerate dissolved in binary methanol and benzene mixtures, Journal of Chemical &Engineering Data, J. Chem. Eng. Data, 1991, 36 (1), 28–32.
P. Kumawat, R. Sharma and Sharma A.K. Spectral, antimicrobial, TGA and photocatalytic degradation studies of copper neem–urea complex using synthetic, nano and doped ZnO, Int. J Environ An. Ch. 2019 (In Press).
S. K. Upadhyaya, Acoustical Study and Thermodynamics of Dissociation and Micellization of Lanthanum and Cerium Linoleates in A Mixture of Benzene and Methanol, Phy. Chem. Liq., 2006, 25, 185-199.
A.K. Sharma, M. Saxena, R. Sharma, Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes,Bull. Pure Appl. Sci. 2017, 36(2), 26-37.
S. Sharma, R. Sharma, S. Goyal S. and A.K. Sharma, Langmuir–Hinshelwood (L– H) adsorption isotherm and photo degradation of copper surfactants derived from saturated fatty acid catalyzed by zinc oxide, Indian Chem. Soc. 2019, 96, 281-288.
P. Tank, R. Sharma, A.K., Sharma, Thermal Behaviour and Kinetics of Copper (II) Soaps and Complexes Derived from Mustard and Soyabean Oil, J. Anal. Pharm. Res. 2017, 4 (2) 1-5. 27. R. Bhutra, R. Sharma, A.K. Sharma, Fungicidal Activities of Cu (II) Soaps Derived From Various Oils Fried at High Temperature for Biomedical Use. SAJ Biotechnol 2018, 5 1-6. 28. P. Tank, R. Sharma, A. K. Sharma, Studies of Ultrasonic and acoustic parameters of complexes derived from Copper (II) surfactant of mustard oil with N and S atoms containing ligands in non- aqueous media (benzene) at 303.15 K. J. Acous. Soc. Ind., 2017, 44(2), 87-99. 29. R. Bhutra, R. Sharma and A.K. Sharma, Viscometric and CMC studies of Cu (II) surfactants derived from unfried and fried groundnut and mustard oils in non-aqueous solvent at 298.15 K J. Inst. Chemists (India), 2017, 90, 29-47.
P. Tank, R. Sharma, A. K. Sharma, Micellar Features and Various Interactions of Copper Soap Complexes Derived from Edible Mustard Oil in Benzene at 303.15 K Curr. Phy. Chem., 2018, 8(1), 46-57.
A.K. Sharma, M. Saxena, R. Sharma, Ultrasonic studies of Cu (II) Soaps derived from Mustard and Soybean oils. J. Pure Appl. Ultrason, 2017, 39(3), 92-99.
K. Tandon, Ultrasonic Studies on Micellar Behaviour of Yttrium Soaps in Mixed Organic Solvents, Phys. Chem. Liq., 2006, 25, 177-184.
P. Tank, R. Sharma, A.K. Sharma, A.K., Viscometric Studies of Cu (II) surfactants derived from mustard oil in benzene at 303.15K, Tenside Surf Det. 2019, 56(2), 158-163. 34. S. Khan, R. Sharma and A.K. Sharma, Volumetric and viscometric studies of copper surfactant derived from Karanj (Pongamia pinnata) oil in methanol-benzene mixture at 298.15 K.J of Phy. Sciences 2019, 50(2) 51-68.
N. Mathur, B. Manna, and A.K. Sharma, Kinetics and thermodynamics of thermal degradation and antimicrobial activity of zinc phenothiazine oleate complex, Bulletin of Pure and Applied Sciences 2019, 36(2), 13-26.
