Synthesis and Characterization of New Sandwiched and multi Decker Palladium Organometallic Compounds of alkylated S-Indacene

Authors

  • Pasha K M Mussuvir Department of Chemistry, Vijayanagara Sri Krishnadevaraya University, Jnana Sagara Campus, Ballari, Karnataka-583105, India
  • Mallikarjuna G Patil PG Department of Chemistry, Basaveshwara Science College, Bagalkote Karnataka India.
  • M K Amshumali Assistant Professor, Department of Chemistry/Industrial Chemistry, Vijayanagara Sri Krishnadevaraya university, Jnanasagara campus, Cantonment, Bellary, Karnataka 583105, India

DOI:

https://doi.org/10.48165/

Keywords:

palladium organometallics, s indacene, multidecker, sandwich

Abstract

A synthesis of mono nuclear bis indacene mono  metal compound of type [L-M-L] where (L is 2,6- diethyl-4,8-dimethyl-1,5-dihydro-s-indacene, M=Pd. Pd-bis (ƞ5-2,6-diethyl-4,8-dimethyl-1,5- dihydro-s-indaceneide) [Pd (Ic’H)2], and the  oligomeric form of this compound is successfully  prepared. The prepared compound is of the type  [L-M-L-M-L-M-L] where M= Pd and L =-2,6- diethyl-4,8-dimethyl-1,5-dihydro-s-indaceneide)}]  [Ic’Pd(µ-Ic’) Pd (µ-Ic’)PdIc’] the reaction yields a  almost quantitative yield. The synthesized  compounds were characterized by NMR (1H and 13C), and elemental analysis. The spectroscopic  data reveals the formation Multidecker  compound. This oligomer is further subjected to  catalytic property study 

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Published

2019-05-05

Issue

Vol. 38 No. 1 (2019): Bulletin of Pure and Applied Sciences Chemistry (Jan-Jun) 2019

Section

Articles

How to Cite

Synthesis and Characterization of New Sandwiched and multi Decker Palladium Organometallic Compounds of alkylated S-Indacene . (2019). Bulletin of Pure and Applied Sciences-Chemistry , 38(1), 89–94. https://doi.org/10.48165/