Volumetric and viscometric studies of copper soap urea complex derived from various vegetable oils in methanol benzene mixture.

Authors

  • Arun Kumar Sharma Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India
  • Meenakshi Saxena Department of Chemistry, S.D. Govt. College, Beawar-305901, Rajasthan, India
  • Rashmi Sharma Department of Chemistry, S.P.C. Govt. College, Ajmer-305001 Rajasthan, India

DOI:

https://doi.org/10.48165/

Keywords:

Cu(II) soap urea complex, edible oils, soap- solvent interaction, CMC, density and viscosity

Abstract

The density and viscosity of Cu (II) soap urea  complex derived from four edible oils (mustard,  groundnut, sesame, soyabean) in non-aqueous  solvents of varying composition has been  determined at constant temperature. The results  were used to determine the critical micelle  concentration (CMC), soap-solvent interactions  and the effect of chain length of the soap urea  complex molecule on various parameters. The  CMC values in higher volume % of methanol are  higher those in higher volume % of benzene, with  regards to chain length of the soap urea complex  CMC value follow the order: CSoU>CSeU> CGU > CMU The conclusions with regard to soap- urea  complex and soap- solvent interaction have been  discussed in terms of well-known Masson’s and  Jones- Dole equations. This vital information  plays an important role in various industrial and  biological applications. 

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References

Tank, P., Sharma, A.K., Sharma, R. (2017). Thermal Behaviour and Kinetics of Copper (II) Soaps and Complexes Derived from Mustard and Soyabean Oil. J. Anal. Pharm. Res., 4(2), 1-5. https://doi.org/10.15406/japlr.2017.04.00102

Pawar, N.R. and Chimankar, O.P.: Comparative study of ultrasonic absorption and relaxation behavior of polar solute and non-polar solvent,J Pure Appl. Ultrason.34 (2012) 49-52. 3. Sharma, S., Sharma, R., Sharma, A.K. (2017). Synthesis, Characterization, and thermal degradation of Cu (II) Surfactants for sustainable green chem. Asian J. Green Chem., 2(2), 129- 140. https://doi.org/10.22631/ajgc.2017.95559.1015

Sivakumar, V., Verma, R.V., Rao, P.G. and Swaminathan, G.:Studies on the use of power ultrasoundin solid liquid myrobalan extraction process. J Clean Prod. 15 (2007) 1813-1818; DOI.org/10.1016/j.jclepro.2006.06.006

Joram, A., Sharma, R. and Sharma, A.K.:Thermal degradation of complexes derived from Cu (II) groundnut soap (Arachishypogaea) and Cu (II) sesame soap (Sesamumindicum), Z phys.Chem. 232(4) 459–470https://doi.org/10.1515/zpch-2017-1073

Nath, G.: Ultrasonic Study of Binary Mixture of Acetone with Bromobenzene and Chlorobenzene at Different Frequencies, Chem. Sci. Trans. 1(3) (2012) 516-521; https://DOI:10.7598/cst2012.171 7. Sharma, S., Sharma, R., Heda, L.C., and Sharma, A.K. (2017). Kinetic parameters and Photo Degradation studies of Copper Soap derived from Soybean Oil using ZnO as a Photo catalyst in Solid and Solution Phase. J. Inst. Chemists (India), 89 (4), 119-136.

Rashmi S, Arun K S. (2017). Natural Edible Oils: Comparative Health Aspects of Sesame, Coconut, Mustard (Rape Seed) and Groundnut (Peanut) A Biomedical Approach. Biomed J Sci. & TechRes.,1(5),BJSTR.MS.ID.000441

https://doi.org/10.26717/BJSTR.2017.01.000441

Palani, R. and Balakrishnan, S.: Acoustical properties of ternary mixtures of 1-alkanols in di isopropyl ether and 2, 2, 2-trifluoroethanol mixed solvent, Indian J. Pure Appl.Phys.48 (2010) 644- 650.

Sharma A.K. Sharma R. Gangwal A.K. 2018. Antifungal activities and characterization of some new environmentally safe Cu (II) surfactants substituted 2-amino-6-methyl benzothiazole. Open Phar Sci. J. 1-11 3-12 https://DOI:10.2174/187484490180501

Kanhekar, S.R., Pravina, P., and Govind, K.B., Thermodynamic properties of electrolytes in aqueous solutions of glycine at different temperatures, Indian J. Pure Appl. Phys.48 (2010) 95-99. 12. Tank, P. Sharma R. Sharma A. K. (2017). A Pharmaceutical approach & Antifungal activities of Copper Soaps with their N & S donor complexes derived from Mustard and Soyabean oils. Glob. J Pharmaceu.Sci.,3(4),GJPPS.MS.ID.555619 https://doi.org/10.19080/GJPPS.2017.03.555619 13. Sharma, A. K. Saxena, M. Sharma R. (2017) Synthesis, spectroscopic and fungicidal studies of Cu (II) soaps derived from groundnut and sesame oils and their urea complexes Bulletin of Pure and Applied Sciences 36(2), 26-37.https://DOI10.5958/2320-320X.2017.00004.8

Thirumaran, S., and Inbam, P.: Thermodynamic and transport studies on some basic amino acids in aqueous sodium acetate solutions at different temperatures, Indian J. Pure Appl. Phys.49 (2011) 451-459.

A. K. Sharma, R. Sharma, M. Saxena (2018) Biomedical and antifungal application of Cu(II) soaps and its urea complexes derived from various oils. Open access J Trans Med res 2(2) 40-43. https://Doi:10.15406/oajtmr.2018.02.00033

Sharma A.K., Sharma R., Gangwal A. Biomedical and fungicidal application of copper surfactants derived from pure fatty acid, Organic & Medicinal Chem. IJ 5(5): OMCIJ.MS.ID.555680 (2018) 1-4 https://DOI:10.19080/OMCIJ.2018.05.555680.

Mathur, N., Ojha, K.G., Imran, A., and Saxena, P.: Viscometric Behaviour and Micellization of Complexes of Copper (II) Stearate with N-donor Heterocyclic Dyes, Tenside Surf. Det. 46 (2009) 24-30; http://DOI:10.3139/113.110004

Naik, A.B., and Narwade, M.L.: Molecular Interactions in Substituted Pyrimidines-Acetonitrile Solutions at 298.15-318.15 K, Russian J. Phy. Chem. A.88(1) (2014) 37-41; http://DOI:10.1134/S0036024414010324

A. K. Sharma, N. Singh and M. Saxena, Synthesis, spectroscopic and biocidal activity of Cu (II) sesame complex “ISBN 978-620-2-09609-6”LAP Lambert Academic Publishing Germany (2017)

M. Saxena, R. Sharma and A.K. Sharma Micellar Features of Cu (II)Surfactants derived from Edible Oils “ISBN 978-620-2-01906-4” LAP Lambert Academic Publishing Germany (2017) 21. D.O. Masson, Solute molecular volumes in relation to solvation and ionization, Philos. Mag., 1929, 8, 218-235.

Khan S. Sharma R. and Sharma A.K. (2018) Acoustic studies and other Acoustic Parameters of Cu(II) Soap derived from non -edible Neem oil (Azadirectaindica), in Non-aqueous media at 298.15 Acta Ac united Ac104, 277-283. https://DOI10.3813/AAA.919170.

Sharma, A.K., Saxena, M., and Sharma, R.: Ultrasonic studies of Cu (II) Soaps derived from Groundnut and Sesame oils, Tenside. Surf. Det. 55(2), (2018) 127- 134https://doi.org/10.3139/113.110544

Tank, P., Sharma, R., Sharma, A.K.: (2018) Micellar Features and Various Interactions of Copper Soap Complexes Derived from Edible Mustard Oil in Benzene at 303.15 K Curr. Phy. Chem. 8(1) 46-57;

https://DOI10.2174/1877946808666180102152443

Sharma AK, Sharma R, Gangwal A. Das D. (2018) CMC, solute-solvent interaction of ternary system containing copper soap-2-amino-6-chloro benzothiazole complex, benzene and methanol at 298.15 K Inst chem. India 90, 121-135.

Bhutra R. Sharma R. Sharma A.K Volumetric studies of copper soap derived from treated and untreated oils in benzene at 298.15 K Bulletin of Pure and Applied Sciences Section-C-Chemistry (2018) 37(2), 33-44

https://DOI10.5958/2320-320X.2018.00028.6

Bhutra R. Sharma R and Sharma A.K. (2017) Viscometric and CMC studies of Cu(II) surfactants derived from untreated and treated groundnut and mustard oils in non-aqueous solvent at 298.15 K J. Inst. Chemists (India), 90, 29-47.

Jones, G. and Dole, M., The viscosity of aqueous solutions of strong electrolytes with special reference to Barium chloride, J. Am. Chem. Soc. 51 (1929) 2950-2964, http://DOI:10.1021/ja01385a012

Sharma A.K. Khan S. Sharma R. Viscometric Behaviour and Micellar Studies of Cu (II) surfactant derived from Neem (Azadirecta Indica)) oil in methanol-benzene mixture at 298.15 K. Global

Meenakshi Saxena

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Published

2019-02-02

Issue

Vol. 38 No. 1 (2019): Bulletin of Pure and Applied Sciences Chemistry (Jan-Jun) 2019

Section

Articles

How to Cite

Volumetric and viscometric studies of copper soap urea complex derived from various vegetable oils in methanol benzene mixture . (2019). Bulletin of Pure and Applied Sciences-Chemistry , 38(1), 1–12. https://doi.org/10.48165/