Role of Iso Amyl Alcohol (IAA) on CO2O3 Catalysed Autoxidation of SO2 in Atmospheric Water

Authors

  • S Begam Department of Chemistry Govt. P. G. College, Jhalawar, Rajasthan 326001, India
  • F Hussain Department of Chemistry Govt. P. G. College, Jhalawar, Rajasthan 326001, India
  • P S N Prasad Associate Professor, Department of Chemistry Govt. P. G. College, Jhalawar, Rajasthan 326001, India

DOI:

https://doi.org/10.48165/

Keywords:

Kinetics, Autoxidation, SO2, CO2O3, Catalysis, Inhibition, IAA

Abstract

The kinetics of the iso amyl alcohol inhibited  CO2O3 catalysed autoxidation of sulfur (IV) in  alkaline medium has been studied and based on  the observed results rate law and a free radical  mechanism has been proposed.  

Downloads

Download data is not yet available.

References

Prasad, D.S.N., Mehta, R.K., Parashar, P., Madnawat, P.V.S., Rani, A., Singh, U., Manoj, S.V., Bansal, S.P., Gupta, K.S., (2003). Kinetics of surface-catalysed autoxidation of aqueous sulfur dioxide in cobalt (III) oxide suspensions. J. Indian Chem. Soc., 80: 391-394.

Prasad, D.S.N., Rani, A., Gupta, K.S. (1992).Surface-catalyzed oxidation of S (IV) in aqueous silica and copper (II) oxide suspensions. Environ. Sci. Technol. 26: 1361-1368.

Gupta, K.S., Singh, R., Saxena, D., Manoj, S.V., Sharma, M., (1999). Role of manganese dioxide in the autoxidation of sulfur (IV) in oxic and anoxic suspensions Ind. J. Chem., 38A: 1129-1138. 4. Sharma, A.K. Sharma, Sharma, R. and Prasad, D.S.N., (2017). Acid rain chemistry, Catalysis and Inhibition of SO2 in environment” ISBN 978-3-659-91204-7”LAP Lambert Academic Publishing Germany.

Gupta, K.S., Jain, U., Singh, A., Mehta, R.K., Manoj, S.V., Prasad, D.S.N., Sharma, A., Parashar, P., Bansal, S.P., (2004). Kinetics and mechanism of the osmium (VIII)-catalysed autoxidation of aqueous sulfur dioxide in acidic and alkaline media. J. Indian Chem. Soc., 81: 1083-1092.

Mudgal, P.K., Sharma, A., Mishra, C.D., Bansal, S.P., Gupta, K.S. (2008). Kinetics of ammonia and ammonium ion inhibition of the atmospheric oxidation of aqueous sulfur dioxide by oxygen. J. Atmos. Chem., 61: 31-55.

Sharma, A.K., Prasad, D.S.N., Sharma, R., (2018). Catalysis and Inhibition of SO2 in Atmospheric Environment- A perspective of acid rain chemistry “ISBN978-93-86841-59-9” chapter published in book entitled Analytical techniques in Chemical and biological sciences Discovery publishing house Pvt. Ltd New Delhi India.

Sharma, A.K., Acharya, S., Sharma, R., Saxena, M., (2012). Recovery and Reuse of SO2 from Thermal Power Plant Emission(Chapter), in Book entitled Air Pollution - Monitoring, Modelling, Health and Control, Dr. Mukesh Khare (Ed.), ISBN: 978-953-51-0381-3, DOI: 10.5772/32390. In Tech Open Access Publisher, University campus Croatia.

[66] Sharma, H., Sharma, A.K., Kumar, M. and Prasad, D.S.N. (2019). The Influence of Succinic Acid on the Kinetics of the Atmospheric Oxidation of Dissolved SO2 Catalysed by Co2O3. International Journal on Emerging Technologies, 10(3): 82-86.

Manoj, S.V., Mishra, C.D., Sharma, M., Rani, A., Jain, R., Bansal, S.P., Gupta, K.S., (2000). Iron, manganese and copper concentrations in wet precipitations and kinetics of the oxidation of SO2 in rain water at two urban sites, Jaipur and Kota, in western India. Atmos. Environ., 34: 4479-4486.

Ghosh, M. K., and Rajput, S.K. (2012).Kinetics and Mechanism of Lanthanum (III) Catalysed Oxidation of D-galactose by Cerium (IV) in Aqueous Acidic Medium, J Applicable Chem., 1(4): 541-550.

Meena,, V., Dayal,Y.,Saxena, D. , Rani, A., Chandel, C.P., Gupta, K.S., (2016).The influence of diesel—truck exhaust particles on the kinetics of the atmospheric oxidation of dissolved sulfur dioxide by oxygen. Environ Sci Pollut Res., 23(17): 17380-92.

Meena, V., Dayal, Y., Rathore, D.S., Chandel, C.P., Gupta, K.S., (2017). Inhibition of Aquated Sulfur Dioxide Autoxidation by Aliphatic, Acyclic, Aromatic,and Heterocyclic Volatile Organic Compounds Int. J. Chem. Kine. 49(4): 221-233.

Meena,, V., Dayal,Y., Rathore, D.S., Chandel, C.P., Gupta, K.S., (2017).Inhibition of atmospheric aqueous phase autoxidation of sulphur dioxide by volatile organic compounds: mono-, diandtri-substituted benzenes and benzoic acids. Prog. React Kinet and Mech., 42(2): 111–125.

Wilkosz, I., Mainka, A., (2008). Mn (II)-catalysed S (IV) oxidation and its inhibition by acetic acid in acidic aqueous solutions. J Atmos. Chem., 60: 1-17.

Ziajka, P. and Pasiuk-Bronikowska, W., (2003). Autoxidation of sulfur dioxide in the presence of alcohols under conditions related to tropospheric aqueous phase, Atmos. Environ, 37: 3913- 3922.

Podkrajsek, B., Grgic, I., Tursic, J., Bercic, G., (2006). Influence of atmospheric carboxylic acids on catalytic oxidation of sulfur (IV). J Atmos. Chem., 54: 103-120.

Gupta, K.S. (2012). Aqueous phase atmospheric oxidation of sulfur dioxide by oxygen: role of trace atmospheric constituent’s metals, volatile organic compounds and ammonia. J. Indian Chem. Soc., 89: 713-724.

Sharma, A.K., Sharma, R., Prasad, D.S.N., Parashar, P. and Gupta, A.K. (2015).Formic Acid inhibited Ag (I) Catalysed Autoxidation of S (IV) in Acidic Medium, J. Chem. Chem. Sci., 5(12): 760-771.

Sharma, A.K., Sharma, R., Prasad, D.S.N., Parashar, P. and Gupta, A.K. (2016). Ag (I) catalyzed autoxidation of S (IV) and its inhibition by isopropyl alcohol in acidic medium.Chem. Sci. Rev. Lett., 17(5): 14-23.

Sharma, A.K., Sharma, R., Prasad, D.S.N., (2015). Kinetics and mechanism of uncatalysed and Ag (I) catalysed autoxidation of S (IV) and its inhibition by isoamyl alcohol in acidic aqueous solutions, Int. J. Mod. Sci. Eng. Technol., 2(12): 31-40.

Sharma, A.K., Sharma, R., Prasad, D.S.N., Parashar, P. (2016). The Inhibitive action of Aniline on the autoxidation of sodium sulfite in acidic medium. J. Anal. Phar. Res., 17(5):14-23. 23. Sharma, A.K., Sharma, R., Prasad, D.S.N.,(2017). The effect of atmospheric aromatic amides

on the Ag (I) catalyzed S (IV) autoxidation in aqueous solution. The Experiment, 40(1): 2354- 2363.

Sharma, A.K., Sharma, R., Prasad, D.S.N., Parashar, P. (2017). Ag (I) catalyzed oxidation of S(IV) in aqueous solution differing effect of benzoate ions in acidic medium, Curr. Phy. Chem. 7(2):338-347.

Sharma, A.K. and Prasad, D.S.N. (2017). Influence of pH and Organics on Autoxidation of S(IV)Catalyzed by Ag (I). Recent Adv. Petrochem Sci., 3(1): 1-2.

Prasad, D.S.N., Rani, A., Madnavat, P.V.S., Bhargava, R., Gupta, K.S. (1991). Kinetics of surface catalyzed oxidation of sulfur (IV) by dioxygen in aqueous suspensions of cobalt (II) oxide. J. Mol. Catal., 69: 395-405.

Sharma, H., Sharma, A.K. and Prasad, D.S.N. (2018). Kinetics and Mechanism of oxalic acid inhibited and heterogenous CO2O3catalysed autoxidation of S (IV) in atmospheric water. J app Chem. 7(5): 1442-1449.

Hussain, F., Begam, S., Singh, J., Sharma, A.K. and Prasad, D. S. N. (2018). Kinetics of aniline inhibited uncatalysed and CO2O3catalysed autoxidation of S (IV) in atmospheric environment. Asian J Chem. Env. Res.11: 60-67.

Hussain, F., Begam, S., Sharma, A.K. and Prasad, D. S. N. (2018). Effect of isopropyl alcohol on autoxidation of S (IV) catalyzed by CO2O3 in alkaline medium. Bull. Pure appl. Sc. 37(1): 9- 18.

Hussain, F., Begam, S., Sharma, A.K. and Prasad, D. S. N. (2018). Co2O3 catalyzed oxidation of SO2 in aqueous solution differing effect of benzamide in alkaline medium. Chem. Sc. Trans., 7(4): 600-609.

Hussain, F., Begam, S., Sharma, A.K. and Prasad, D. S. N. (2018). Kinetics and Mechanism of Co2O3 catalysed autoxidation of sulphite and inhibition by sodium benzoate, J. Inst. Chemists (India) 90(4):104-119.

Begam, S., Hussain, F., Singh, J., Sharma, A.K. and Prasad, D.S.N. (2018).Kinetics of sodium sulphite oxidation catalyzed by Co2O3 and inhibited by ethylene glycol. Asian J res chem., 11(3): 610-616.

Sharma, H., Sharma, A.K., Parashar, P. and Prasad, D.S.N. (2019). Effect of acetic acid on Co2O3 catalyzed autoxidation of aqueous sulphur dioxide in alkaline medium Sch. Acad. J. Biosci. 7(3): 117-124.

Sharma, A.K., Sharma, R., Prasad, D.S.N. (2017). Role of organics in Atmospheric Catalytic Autoxidation of Aqueous Sulphur Dioxide in acidic Medium. Malaysian J. Chem. 19(1):1–12. 35. Sharma, A.K., Sharma, R. and Prasad, D.S.N. (2017). Kinetics of isoamyl alcohol and aniline inhibited uncatalysed and Ag (I) catalysed autoxidation of S (IV) in acidic Medium. Asian J. Res. Chem., 10(3): 251-258.

Sharma, A.K., Sharma, R. and Prasad, D.S.N. (2018). Effect of Aliphatic Mono Carboxylic acids and alcohols on Ag (I) Catalyzed oxidation of SO2 in aqueous solution, J Mat. Env. Sci. 9(6): 1829-1837.

Bhargava, R., Prasad, D.S.N., Rani, A., Bhargava, P., Jain, U., and Gupta, K.S. (1993). Kinetics of autoxidation of aqueous sulphur dioxide in suspensions of nickel (III) oxide. Transit. Metal Chem., 17: 238-241.

Sharma A.K. Kinetics and Mechanism of the Silver (I)-Catalyzed Autoxidation of SO2 in Aqueous Solution and Its Inhibition by Benzoate and Amide Ions (2018) Bulletin of Pure and Applied Sciences. 37 C (2):, 82-92.

Sharma, A.K., and Prasad, D.S.N. (2020). Copper Catalyzed Autoxidation of Sulphur Di Oxide and Inhibition by Methanoic Acid. Current Phy chem. 10, 33-46.

Sharma, H., Sharma, A.K. and Prasad, D.S.N. (2019). Dynamics Of Malonic Acid Inhibited Uncatalysed And Co2O3catalysed Autoxidation Of S (IV) In Alkaline Medium. Think India Journal. 22(14): 7168-7181.

Downloads

Published

2020-05-12

Issue

Vol. 39 No. 1 (2020): Bulletin of Pure and Applied Sciences Chemistry (Jan-Jun) 2020

Section

Articles

How to Cite

Role of Iso Amyl Alcohol (IAA) on CO2O3 Catalysed Autoxidation of SO2 in Atmospheric Water . (2020). Bulletin of Pure and Applied Sciences-Chemistry , 39(1), 38–49. https://doi.org/10.48165/