Micellar and Viscometric Properties of Some Bioactive Copper Soaps Derived From Karanj Oil in Non - Polar Solvent

Authors

  • Shema Khan Department of Chemistry, S.R.K.P. Govt. P.G. College Kishngarh-305801, Rajasthan, India.
  • Rashmi Sharma Department of Chemistry, S.P.C. Govt. College, Ajmer-305001 Rajasthan, India.
  • Arun Kumar Sharma Department of Chemistry, Govt. P.G. College, Jhalawar-326001, Rajasthan, India

DOI:

https://doi.org/10.48165/

Keywords:

Cu(II) surfactant, karanj oil, Soap solvent interaction, CMC, Viscosity

Abstract

The viscosity, specific viscosity, and fluidity of  Cu (II) surfactant derived from karanj oil in non polar and polar solvent mixture have been  determined at constant temperature 303.15 K.  The results were used to determine the critical  micelle concentration (CMC), solute-solvent  interactions and the effect of chain length of the  surfactant molecule on different parameters. The  conclusions have been discussed in terms of well known Moulik’s and Jones- Dole equations. The  effect of surfactant concentration on viscosity of  the solution in solvent mixtures with different  polarityhas been discussed. The observations  suggested that the structure breaking effect by  the solute on the solvent molecules is more  prominent above CMC as compared to below  CMC after the formation of the micelles. These  study helps in interpretation of solute solvent  interactions, structural insight of micelle and  colloidal chemical behavior in binary/ternary  systems. Study of these factors is essential as it  indirectly makes them responsible for their  immense applicability in wide areas of field. The  vital information plays an important role for the  selection of the synthesized bio-molecule in  various research and development fields.  

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References

A. Joram, R. Sharma, and A.K. Sharma, Z phys. Chem., 232, 459, (2018). 2. N. Mathur, N. Jain, and A.K. Sharma, Open Phar Sci. J. 5 24, (2018).

A.K. Sharma, M. Saxena, and R. Sharma, Open Chem. J. 5, 89, (2018).

S. Sharma, R. Sharma and A.K. Sharma, Current Env. Eng. 5, 221, (2008). 5. A.K. Sharma, R. Sharma, and A. Gangwal, Current Phy chem. 8(2), 151, (2018). 6. V.P. Mehta, P.R. Talesara, R. Sharma, Ind. J chem. 40, 399, (2001).

K.N. Mehrotra, K. Tonton, M.K. Rawat, Colloids and Surf., 57(1), 125, (1991). 8. A. Joram, R. Sharma, and A.K. Sharma, Open chem. J. 5, 145, (2018).

N. Mathur, N. Jain, and A.K. Sharma, Open chem. J. 5, 182, (2018).

R. Bhutra, R. Sharma, and A.K. Sharma, Open Pharm Sci J. 5, 36, (2018). 11. A.K. Sharma, R. Sharma, and A. Gangwal, Open Phar Sci. J. 5, 3, (2018). 12. S. Khan, R. Sharma, A.K. Sharma, Malaysian J. Chem., 19(2) ,99, (2017).

K.N. Mehrotra, M. Jain, Colloids Surf A Physicochem Eng Asp.1994, 85, 75-80. 14. J.A. Siddique, S. Sharma, S. Naqvi, Arabian J Chem., 9(2), 1040, (2016).

A.K. Sharma, M. Saxena, R. Sharma, Tenside. Surf. Det., 55(2), 127, (2018). 16. M. M. R., Meor Mohd Affandi, M. Tripathy, & A. B. A. Majeed J. Mol. Liq., 223, 1093, (2016). 17. S. Khan, R. Sharma, A.K. Sharma, Acta. Ac united Ac, 104, 277, (2018).

A.K. Sharma, M. Saxena, and R. Sharma, J of Phy. Sciences.29(3) 67, (2018). 19. Y. Akhtar, Fluid Phase Equilib, 258(2), 125, (2007).

A.K. Sharma, R. Sharma, A. Gangwal, and D. Das, J Inst chemists (India), 90(4), 121, (2018). 21. K.N. Mehrotra, M. Chauhan, R.K. Shukla J Am. Oil chemist soc. 67(7), 446, (1990). 22. R. Bhutra, R. Sharma, and A.K. Sharma, Bull Pure & Appl. Scie. Chem. 37(2), 33, (2018). 23. A. K. Sharma, S. Khan, and R. Sharma, Global J. Eng. Sci. Res. FRTSSDS, 9, (2018). 24. A. Einstein, Ann Phys., 19, 289, (1906).

D. J. Thomson, J. Colloid Sci., 20, 267, (1965).

V. Vand, J. Phys. Chem., 52, 277, (1948).

S. P. Moulik, J. Phys. Chem., 72, 74, (1968).

V.R. Gray and A.E. Alexander, J. Phys. Coll. Chem.53, 9, (1949).

G. Jones, and M. Dole, J. Am. Chem. Soc. 51, 2950, (1929).

S. Khan, R. Sharma, A.K. Sharma, Cu Surfactants derived from Non- Edible oils: Bio Chemical aspects” ISBN 978-620-2-00001-7” LAP Lambert Academic Publishing, Germany, 2017.

P. Tank, R. Sharma, A. K. Sharma, Curr. Phy. Chem., 8(1), 46, (2018).

R. Bhutra, R. Sharma and A.K. Sharma, J. Inst. Chemists (India), 90(3) 66, (2018). 33. A.K. Sharma, M. Saxena, and R. Sharma, Open chem. J. 5, 119, (2018).

R. Bhutra, R. Sharma and A.K. Sharma, J. Inst. Chemists (India), 90, 29, (2017). 35. A.K. Sharma, M. Saxena, R. Sharma, J. Pure Appl. Ultrason, 39(3), 92, (2017). 36. K. Rajagopal, S.S. Jayabalkrishnan, Chainese J Chem. Eng. 18(3), 425, (2010). 37. P. Tank, R. Sharma, A. K. Sharma, J. Acous. Soc. Ind., 44(2), 87, (2017).

R. Bhutra, R. Sharma and A.K. Sharma, Malaysian J Chem. 20(2), 163, (2018).

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Published

2020-06-02

Issue

Vol. 39 No. 1 (2020): Bulletin of Pure and Applied Sciences Chemistry (Jan-Jun) 2020

Section

Articles

How to Cite

Micellar and Viscometric Properties of Some Bioactive Copper Soaps Derived From Karanj Oil in Non - Polar Solvent . (2020). Bulletin of Pure and Applied Sciences-Chemistry , 39(1), 1–13. https://doi.org/10.48165/