Corrosion Inhibitive Effects of Coconut Water for Al 7075 Alloy in Acidic Medium

Authors

  • R D Pruthviraj Department of Chemistry, Rajarajeswari College of Engineering, Mysore Raod, Bangalore, Karnataka 560074, India
  • K C Vishwanath Department of Mechanical Engineering,, Rajarajeswari College of Engineering, Mysore Raod, Bangalore, Karnataka 560074, India
  • A A Jahagirdar Department of Chemistry, Dr. Ambedkar Institute of Technology, Mallathalli, Bangalore, Karnataka 560056, India
  • M T Swamy Department of Chemistry, Sambhram Institute of Technology, Vidyaranyapura, Bangalore, Karnataka 560056, India
  • S D Ashok Department of Chemistry, R & D Centre for Nano Science and Nano Technology, Global Academy of Technolohy, RR Nagar, Bangalore, Karnataka 560098, India

DOI:

https://doi.org/10.48165/

Keywords:

Coconut water, inhibitive effect, Al 7075 alloy, H2SO4, corrosion rate

Abstract

The corrosion inhibitive effect of coconut water  as an eco-friendly inhibitor for the corrosion  control of Al 7075 alloy in 0.5 Molar solution of  H2SO4 acid have been investigated using the  weight loss method which is considered more  informative than other laboratory techniques.  The studies were carried out using 30-110ml of  the coconut water. The test coupons were totally  immersed in the corroding medium containing  various concentration of the inhibitor at the time  intervals of 24-192 hours. The results obtained  showed that the concentration of the inhibitor in  the corrodent impacted differently on the test  coupons. The corrosion rate was found to  decrease while the inhibitor efficiency increases  as the inhibitor concentration was increased. The  plateau of maximum inhibition efficiency of  89.07% and 81.57% was obtained at the  concentration of 90ml and 110ml for 24hours and  48hours immersion time respectively. The study  showed that coconut water possesses inhibiting  properties for reducing the corrosion of Al 7075  alloy in the acidic medium. 

Downloads

Download data is not yet available.

References

Baldev Raj, V. Shankar, and A.K. Bahaduri (2012), Welding technology for engineers. Published by Narosa publishing house, pvt. Pp.183.

Lekan Taofeek Popoola, Alhaji Shehu Grema, Ganiyu Kayode Lantinwo, Babagana Gulti and Adebori Saheed Balogun (2013). Corrosion problems during oil gas production and its mitigation. International Journal of Industrial Chemistry (IJIC). 2013,4:35.

Vijendra Singh (2011). Physical Metallurgy. Published by A. K. Jain for Standard Publishers Distribution, New Delhi, pp.696-702

Camila, G. Dariva and Alexandre, F. Galio (2014). Corrosion inhibitors: Mechanisms and Applications. Pp.365. Retrieved March 24, 2016 from http://www.wermac.org/images/favicon

.ico

National Association of Corrosion Engineers (2002). Materials Performance, Special Issue, Houston, Texas, USA. Jointly with C. C. Technologies and FHWA.

Al-Otaibi, A. M. Al-Mayouf, M. Khan, A. A. Mousa, S. A. Al-Mazroae H. Z. Alkhathlan (2012), “Corrosion inhibitory action of some plant extracts on the corrosion of Al 7075 alloy in acidic media,” Arabian Journal of Chemistry, pp. 1- 7.

I.B. Obot, N.O. Obi-Egbedi, S.A. Umoren (2009), “Antifungal drugs as corrosion inhibitors for aluminium in 0.1 M HCl,” Corrosion Science, vol. 51, issue 8, pp. 1868- 1875.

A. Yıldırım, M. Çetin (2008), “Synthesis and evaluation of new long alkyl side chain acetamide, isoxazolidine and isoxazoline derivatives as corrosion

inhibitors,” Corrosion Science, vol. 50, issue 1, pp.155-165.

Gentil,V (2003). Corrosão ( 4th ed.), Rio de Janeiro: LTC,

Revie, R. W. and Uhlig, H. H. (2008). Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering. (4th edition), John Willey and Sons, Inc., publication. Pp.303.

Fontanna, M. G. (2007). Corrosion Engineering (3rd ed.). Published by Tata McGraw-Hill Ltd. New Delhi. Pp. 14, 21 and 282.

Corrosion inhibitors (2013). US Industry study with forecasts for 2017 and 2022. Pp.44. Retrieved April 17, 2015 from www.freedonia.com

Adzor, S. A., Adaga, G. T. and Gundu, D. T. (2014). Corrosion inhibitive potential of Hibiscus Sabdariffa calyx extract for low carbon steel in 0.5M H2SO4 acid solution. International Journal of Engineering Sciences and Research, 3(8), pp.133-137.

S. Alarmal Mangai and Subban Ravi (2013). Comparative corrosion inhibition effect of Imidazole compounds and of Trichodesima indicum (Linn) R. Br. On C38 steel in 1M HCl medium. Journal of chemistry, vol. 2013 (2013).pp.1

Suleiman, I. Y., Oloche, O. B. and Yaro, S. A. (2011). The potential of using Acacia Sengalensis extract as corrosion inhibitor for carbon steel in 0.5M H2SO4 medium. Proceedings of the Nigerian Metallurgical Society, 27th Annual Conference and General Meeting. Pp. 177-186.

F. A. Ayeni, V.S. Aigbodion and S. A. Yaro (2007). Non-Toxic Extract as Corrosion Inhibitor for Chill Cast AL-Zn-Mg Alloy in Caustic Soda Solution. Eurasian Chem Tech Journal 9(2007) 91-94.

Deepa Prabhu and Padmalatha Rao (2013). Coriandrum Sativam L.: A novel green inhibitor for the corrosion inhibition of aluminium in 1.0M Phosphoric acid solution. Journal of Environmental Chemical Engineering, vol. 1, issue 4, pp.676-683.

Ambrish Singh, Eno, E. Ebenso, and M. A. Quaraihi (2012). Corrosion inhibition of carbon steel in hydrochloric acid solution by some plant extracts. Hindawi Publishing Corporation. International Journal of Corrosion, vol. 2012. Pp.

Ogoko, E. C., Odoemelam, S. A., Ita, B. I., Eddy, N. O. (2009). Adsorptive and inhibitive properties of Clarithromycin for

the corrosion of Zn in 0.01-o.05M H2SO4. Portugalia Electrochemica Acta 27(6), pp. 713-724.

Hubert Gräfen, Elmar-Manfred Horn, Hartmut Schlecker, Helmut Schindler (2002). "Corrosion" Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH: Weinheim, doi:10.1002/14356007.b01_08

Rajput, R. K. (2010). Material Science and Engineering. Published by S. K. Kataria and Sons, New Delhi. Pp.866.

Khanna, O. P. (2008). Material Science and Metallurgy. Published by Isah Kapur for Dhanpat Rai publications Ltd. Pp.48.

Manish Gupta, Jyotsna Mishra and K. S. Pitre (2013), Corrosion and inhibitive effects of Al 7075 alloy in hydrochloric acid solution containing organophosphoric acid. International Journal of Corrosion, vol. 2013. Pp.1.

S.Papavinasam. Corrosion inhibitors. Canmet materials technology laboratory, Ottawa, Ontario, Canada. Pp1101. View on scholar google.

Pierre, R. R. (2000). Handbook of corrosion Engineering. McGraw-Hill company,Inc. New York.

Janick, J. Paull (2008). R.E. The Encyclopedia of Fruit & Nuts; CAB International: Wallingford, UK, pp. 112.

Sandhya, V.G.; Rajamohan, T. (2008). Comparative evaluation of the hypolipidemic effects of coconut water and lovastatin in rats fed fat-cholesterol enriched diet. Food Chem. Toxicol., 45, 3585–3592.

Asian and Pacific Coconut Community (1994). International Codes and Standard for Aqueous Coconut Products, 2nd draft. Standards Task Force, Jakarta, Indonesia.

Seow, C. C. and Gwee, C.N. (1997). Coconut milk: Chemistry and technology. Int. J. Food Sci. Tech., 32, 189–201.

George, E.F.; Sherrington, P.D. (1984). Plant Propagation by Tissue Culture Handbook and Directory of Commercial Laboratories; Exegetics Ltd: Edington, UK.

Campbell-Falck, D., Thomas, T., Falck, T.M., Tutuo, N., Clem, K. (2000). The intravenous use of coconut water. Am. J. Emerg. Med., 18, 108–111.

Pummer, S., Heil, P., Maleck, W. and Petroianu, G. (2001). Influence of coconut water on hemostasis. Am. J. Emerg. Med., 19, 287–289.

Anurag, P., Rajamohan, T. (2003). Cardioprotective effect of tender coconut water in experimental myocardial infarction. Plant Foods. Hum. Nutr., 58, 1– 12.

Alleyne, T., Roache, S., Thomas, C. and Shirley, A. (2005). The control of hypertension by use of coconut water and mauby: Two tropical food drinks. West Indian Med. J., 54, 3– 8.

Van Overbeek, J., Conklin, M. E. and Blakeslee, A.F. (1941). Factors in coconut milk essential for growth and development of very young Datura embryos. Science, 94, 350– 351.

Verdeil, J.L. and Hocher, V. (2002). Digestion and absorption of food in plants: A plant stomach. Trends Plant Sci., 7, pp. 280–281.

Ang, S. L. P and Yong, J.W .H. (2005). A protocol for in vitro germination and sustainable growth of two tropical mistletoes. Plant Cell Tiss. Org. Cult., 80, 221–228.

Arditti, J. (2008). Micropropagation of Orchids, (2nd ed.), Blackwell Publishing: Oxford, UK, Volume II.

Jean, W. H. Yong, Luya Ge, Yan Fei Ng and Swee Ngin Tan (2009). The Chemical Composition and Biological Properties of Coconut (Cocos nucifera L.) Water. Molecules 2009, 14, 5144-5164; doi: 10.3390/molecules 14125144, pp.5144- 5157.

Bucheishaija, J. (2009). Phytochemicals green corrosion inhibitors in various corrosive media: A Review. Tanzania Journal Sciences, vol. 35. Pp.79-80.

Revie, R. W. and Uhlig, H. H. (2008). Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering. (4th edition), John Willey and Sons, Inc., publication. Pp.303.

Asuke, F., Yaro, S. A. and Oloche, O. B. (2009). Propargyl as corrosion inhibitor for Al- 5% Si-15%SiC Composite in 0.5M Sodium Hydroxide. Proceedings of the 26Th Annual Conference and General Meeting of the Nigerian Metallurgical Society, pp. 85-94.

A.C. Dutra e L. D. P. Nunes (2011). Protecao Catodica tecnicas de Combate a Corrosao, 5ed., Rio de Janero: Interciencias,

E. Bardal (2004). Corrosion and Protection, London Springer.

Published

2021-07-12

How to Cite

Corrosion Inhibitive Effects of Coconut Water for Al 7075 Alloy in Acidic Medium . (2021). Bulletin of Pure and Applied Sciences-Chemistry , 40(1), 7–15. https://doi.org/10.48165/