Excess Molar Volumes of Binary Liquid Mixtures of Ketocyclohexane (C6H10O), + CH2Cl2, +CHCl3, + CH2ClCH2Cl, +CHClCCl2, and + CCl3CH3 at 303.15 K

Authors

  • Atri D Tripathi Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Varun Kumar Singh Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Mahima Purohit Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Kanika Bisht Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Muskan Rajput Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.

DOI:

https://doi.org/10.48165/

Keywords:

Dilatometer, Excess Volume, Specific interaction, Hydrogen bonding, Binary mixtures

Abstract

Excess molar volumes, VE, at T = 303.15 K, have  been measured for binary liquid mixtures of  ketocyclohexane (C6H10O) + dichloromethane  (CH2Cl2), + trichloromethane (CHCl3), + l,2- dichloroethane (CH2ClCH2Cl), + trichloroethene  (CHClCCl2), and + 1,1,1- trichloroethane  (CCl3CH3). The values of VE have been fitted in  appropriate equations using a least-squares  method. VE has been found to be negative  throughout the entire range of composition for  mixtures of C6H10O + CH2Cl2, + CHCl3, +  CHClCCl2, and + CCl3CH3. For C6H10O +  CH2ClCH2Cl, VE has been found to be positive at  lower mole fractions of C 6H10O, and negative at  higher mole fractions. The results obtained have  been discussed from the viewpoint of existence of  specific interactions between the components. 

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References

. Nath J., Tripathi A.D. (1983), Binary Systems of 1 ,I ,2,2-Tetrachloroethane with Benzene, Toluene, p-Xylene, Acetone, and Cyclohexane. 1. Excess Volumes, Ultrasonic Velocities, and Adiabatic Compressibilities at 298.15 and 308.15 K .J. Chem. Eng. Data 1983, 28, 263-268.

. Chadha R., Tripathi A.D.(1995), Excess Molar Enthalpies of 1,1,2,2- Tetrachloroethane + 2-Methylfuran, + Tetrahydrofuran, + 1,4-Dioxane,a nd + Cyclopentanone at 308.15 and 318.15 K. J. Chem. Eng. Data 1995,40, 645-646.

. Pathak G., Tripathi A.D., Phalgune U. D, Pradhan S. D. (1995), Enthalpies of mixing of tetrachloroethane with furan, methyl furan, tetrahydrofuran, cyclopentanone and 1,4,-dioxane. Thermochim. Acta 258:109– 115.

. Riddick, J. A, Bunger, W. B. Organic Solvents; Wiley: New York, 1986.

. Agrawal M., Tripathi A.D. (2014), Excess Molar Volume of Binary Mixtures of Tetrachloroethylene + Acetylacetone, + Acrylonitrile, + Anisole and + Tetrahydrofuran at 303.15 K. Journal of Applied Solution Chemistry and Modeling, 2014, 3, 130-134.

. Tripathi A.D. (2010), Excess Enthalpies of Dibromomethane with Acetone, 1,4- Dioxane, Pyridine, Diethyl Ether, Ethyl Methyl Ketone, and Tetrahydrofuran at 303.15 K, J. Chem. Eng. Data 2010, 55, 1113–1116.

. Magee M. D., Walker S. (1969), Dielectric Studies. XXII. Interaction of Chloroform with Electron-Donor Molecules, J. Chem. Phys., 50, 1019.

. Pimental G. C., McClellan A. L (1960), The Hydrogen Bond (Freeman, San Francisco, 1960).

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Published

2021-07-12

Issue

Vol. 40 No. 1 (2021): Bulletin of Pure and Applied Sciences Chemistry (Jan-Jun) 2021

Section

Articles

How to Cite

Excess Molar Volumes of Binary Liquid Mixtures of Ketocyclohexane (C6H10O), + CH2Cl2, +CHCl3, + CH2ClCH2Cl, +CHClCCl2, and + CCl3CH3 at 303.15 K . (2021). Bulletin of Pure and Applied Sciences-Chemistry , 40(1), 1–6. https://doi.org/10.48165/