Bismuth Nitrate Catalysed Convenient Synthesis of 1,8-Dioxo Octahydro xanthene Derivatives

Authors

  • A Sudhakara Chemistry R & D Centre, Dept of Chemistry, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, Karnataka 560074, India
  • Prabhakara P Varma Chemistry R & D Centre, Dept of Chemistry, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, Karnataka 560074, India
  • R D Pruthviraj Chemistry R & D Centre, Dept of Chemistry, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, Karnataka 560074, India
  • S Ramesha Chemistry R & D Centre, Dept of Chemistry, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, Karnataka 560074, India
  • Pradeep Nair Chemistry R & D Centre, Dept of Chemistry, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, Karnataka 560074, India

DOI:

https://doi.org/10.48165/

Keywords:

Benzaldehydes, 5,5-dimethyl-1, 3-cyclohexane-dione, Bismuth Nitrate, EtOH, 1,8-dioxo octahydroxanthene

Abstract

Synthesis of wide variety of substituted 1, 8-dioxo-octahydro xanthene derivatives from reacting  various Benzaldehydes with 5, 5-dimethyl-1,3-cyclohexane-dione via Bismuth Nitrate [Bi(NO3)3  5H2O] Catalysed reaction is described. The present methodology offers several significant advantages  such as high yields, short reaction times, simple operation and convenient work-up. 

Downloads

Download data is not yet available.

References

. Jamison, J. M.; Krabill, K.; Hatwalkar, A. (1990). Cell. Biol. Int. Rep. 14, 1075. [2]. Hashim, Y. Z. H. Y.; Kerr, P. G.; Abbas, P., Salleh, H. M. Aquilaria spp. (agarwood) as source of health beneficial compounds: A review of traditional use, phytochemistry and pharmacology. J Ethnopharma, 2016, 189, 331-360.

. Sirkecioglu O, Tulinli N, Akar A, (1995). J. Chem. Res. (S) 502.

. Knight CG, Stephenes T, (1989). Biochem. J. 258, 683.

. (a) Hatakeyama S, Ochi N, Numata H, Takano S, (1998). J. Chem. Soc. Commun. 1202. (b) Callaghan CNO and. McMurry TBH. (1995) J. Chem. Res. Synop. 214; (1995) J. Chem. Res. Miniprint, 1448, (C) Wang, HK, Morris-Natschke SL, Lee KH. (1997). Med. Res. Rev, 17, 367-425. (d) Rukavishnikov AV, Smith MP, Birrell GB, Keana JFW, Griffith OH. (1998) Tetrahedron Lett 39, 6637-6640.

. Hideu T, Tokkyo Koho JP Jpn 56005480, (1981) (1981) Chem. Abstr. 95, 80922b).

. Lamberk RW, Martin JA, Merrett JH, Parkes KEB, Thomas GJ, PCT Int. Appl. WO 9706178 (1997) (1997) Chem. Abstr. 126, P212377y).

. Poupelin JP, Saint-Rut G, Fussard Blanpin O, Narcisse G, Uchida-Ernouf G, Lakroix R, (1978) Eur. J. Med. Chem. 13, 67–71.

. (a) Fan X., Hu X., Zhang X., Wang J., (2005) Can. J. Chem. 83, 16–20. (b) Fan X-S, Li Y-Z, Zhang X-Y, Hu X-Y, Wang J-J, (2005) Chin. J. Org.Chem. 25, 1482–

(c). Ma J-J, Li J-C, Tang R-X, Zhou X, Wu Q-H, Wang X,. Zhang M M,. Li Q, (2007) Chin. J. Org. Chem. 27, 640–642.

. (a) Shakibaei GI, Mirzaei P, Bazgir A, (2007). Appl. Catal. A: Gen. 325, 188– 192. (b) Das B, Thirupathi P, Reddy KR, Ravikanth B, Nagarapu (2007). L, Catal. Commun. 8, 535–538. (c) M. Seyyedhamzeh, Mirzaei P, Bazgir A (2008). Dyes Pigm. 86, 836–839. (d) John A, PJP. Yadav SP, (2006). J. Mol.

Catal. A: Chem. 248, 121–125. (e) Das B,. Thirupathi P, Mahender I, Reddy VS, Rao YK, (2006) J. Mol. Catal. A: Chem. 247, 233–239.

. (a) Kantevari S, Bantu R, Nagarapu L, (2006) Arkivoc xvi, 136–148. (b) Jin T S,. Zhang J-S, Xiao J-C, Wang A-Q, Li T-S, (2004) Synlett 866–870 (c) Jin T-S, Zhang J-S, Wang A-Q,. Zhang F-S, (2005) Chin. J Org Chem. 25, 335–338.

. (a) Adharvana Chari M., Shobha D, Kiran Kumar T, and. Dubey PK. (2005). ARKI VOC 2005 (xv), 74-80. (b) Srivastava N, Banik BK, (2003). J Org Chem 68, 2109. (c) Bimal K, Banik and Magda Cardona, (2006). Tetrahedron Letters 47, 7385–7387 (d) Nicholas ML, Laura C and Ram SM (2002). Tetrahedron 58, 8373–8397.

. Sudhakara A, Jayadevappa H, Harish Kumar HN, and Mahadevan KM., (2009). Letters in Organic Chemistry 6, 159-164.

. Hamid Reza shaterian, Asghar Hosseinian and Majid Ghashang, (2009). Turk J Chem 33, 233–240.

. Xue Yuan HU, Xue Sen FAN, Xin Ying ZHANG, Jian Ji WANG, (2005) Chinese Chemical Letters 16(3), 293-295

Downloads

Published

2021-12-15

Issue

Vol. 40 No. 2 (2021): Bulletin of Pure and Applied Sciences Chemistry (Jul-Dec) 2021

Section

Articles

How to Cite

Bismuth Nitrate Catalysed Convenient Synthesis of 1,8-Dioxo Octahydro xanthene Derivatives . (2021). Bulletin of Pure and Applied Sciences-Chemistry , 40(2), 57–62. https://doi.org/10.48165/