Relative Permittivity Behaviour of CH3COCH2CH3 (2-Butanone) with CH2Cl2 , CH2Cl.CH2Cl and CCl2CCl2

Authors

  • Atri Deo Tripathi Department of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India

DOI:

https://doi.org/10.48165/

Keywords:

2-butanone, Relative Permittivity, Dichloromethane, Hydrogen Bonding, Dekameter

Abstract

The experimental data for �� (relative permittivities) and n (refractive indices), were measured for  mixtures of 2-butanone (BN) (CH3COCH2CH3) with dichloromethane (����2����2), 1,2-dichIoroethane (CH2Cl.CH2Cl) and tetrachloroethene (CCl2CCl2) at the temperature 308.15 K. The values of ∆�� which  represent the departures of the �� for the mixtures from the quantities occuring from the law achieved  from mole fraction mixture, have been obtained. Calculated values of ∆�� shows positive sign for BN  with CH2Cl2 and CH2Cl.CH2Cl, whereas it is negative in the case of BN with CCl2CCl2. With the help  of the values of �� and n, the Kirkwood correlation parameter, g, have been calculated for mixtures of  BN with CH2Cl2 and CH2Cl.CH2Cl. The values of g indicate that BN forms intermolecular complexes  with these compounds. The Equilibrium constant Kf, for the creation of complexes (1:1) of BN with  CH2Cl.CH2Cl and CH2Cl2, have also been obtained with the experimental data for ��.  

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References

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Published

2022-06-12

Issue

Vol. 41 No. 1 (2022): Bulletin of Pure and Applied Sciences-Chemistry (Jan-Jun) 2022

Section

Articles

How to Cite

Relative Permittivity Behaviour of CH3COCH2CH3 (2-Butanone) with CH2Cl2 , CH2Cl.CH2Cl and CCl2CCl2 . (2022). Bulletin of Pure and Applied Sciences-Chemistry , 41(1), 1–8. https://doi.org/10.48165/