Adsorption of Cadmium & Zinc on Chemically modified Silica Gel functionalized with linear Poly (amido amine)
DOI:
https://doi.org/10.48165/bpas.2023.42C.1.5Keywords:
Toxicity, Metal ion, Adsorption, PAAsAbstract
The present investigation reports the adsorption of zinc & cadmium on silica surface chemically modified with linear poly (amido amine) a water-soluble polymer. The material is characterized by FTIR spectroscopy & Elemental Analyzer. The efficiency of metal binding of the adsorbent for Cd2+ and Zn2+ have been studied in aqueous solutions of corresponding metal ions. The results showed a valuable aspect of increasing trend.
Downloads
References
Alloway B.J. (1990). Cadmium. In: Alloway, B.J. (Ed), “Heavy Metals in Soils, Blackie, Glasgow and London”, John Wiley & Sons, New York, 100-124.
Bortoleto G.G., Macarovscha G.T., Cadore S. (2004). Determination of cadmium by flame-atomic absorption spectrometry after preconcentration on silica gel modified with cupferron, J. Braz. Chem. Soc. 15 (02), 313 https://dx.doi.org/10.1590/S0103-
Camel V. (2003). Solid phase extraction of trace elements, Spectrochimica Acta Part B: Atomic Spectroscopy, 58 (7), 1177-1233, https://doi.org/10.1016/S0584-
(03)00072-7.
Dey R.K., Airoldi C. (2008) Designed pendant chain covalently bonded to silica gel for cation removal, Journal of Hazardous Materials, 156, (1–3), 95-101.
https://doi.org/10.1016/j.jhazmat.2007.12.0 05.
Dey R.K., Oliveira A.S., Patnaik T., Singh, D. Tiwary V.K., Airoldi C. (2009), Grafting of organosilane derived from 3- glycidoxypropyltrimethoxysilane and thiourea onto magnesium phyllosilicate by sol–gel process and investigation of metal adsorption properties, Journal of Solid State Chemistry, 182(8), 2010-2017, https://doi.org/10.1016/j.jssc.2009.05.011
Dey R.K., Patnaik T., Singh V.K., Swain S.K., Airoldi C. (2009). Attachment of linear poly(amido amine) to silica surface and evaluation of metal-binding behavior, Applied Surface Science 255, 8176 https://doi.org/10.1016/j.apsusc.2009.05.03
Dey R.K., Patnaik T., Singh V.K., Swain S.K., de Melo M.A., Airoldi C. (2010). Al centered functionalized inorganic–organic hybrid sorbent containing N and S donor atoms for effective removal of cadmium, Solid State Sciences, 12(4), 440-447, https://doi.org/10.1016/j.solidstatesciences
.2009.12.005.
Ganjali M.R., Basiripour F., Shamsipur M., Hashemi O.R., Moghimi A., Aghabozorg H. (2003). Ultratrace determination of lead, cadmium and copper in environmental and biological samples by atomic absorption spectrometry after their separation and preconcentration using octadecyl silica membrane disks modified with a new n–s schiff base, Int. J. Environ. Anal. Chem. 83, 997.
https://doi.org/10.1080/0306731000160878 6
Hayashi S., Takeuchi Y., Eguchi M., Iida T., Tsubokawa N. (1999) Graft polymerization of vinyl monomers initiated by peroxycarbonate groups introduced onto silica surface by Michael addition, J. Appl.
Polym. Sci. 71, 1491–1497. http://doi:10.1002/(SICI)1097-4628 (1999 0228)71:9<1491::AID-APP13>3.0.CO;2-M
Jal P.K., Patel S., and Mishra B.K. (2004). Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions, Talanta, 62, 1005. https://doi:10.1016/j.talanta.2003.10.028.
Lagadic I.L., Mitchell M.K., Payne B.D. (2001). Highly effective adsorption of heavy metal ions by athiol-functionalized magnesium phyllosilicate clay, Environ. Sci. Technol, 35, 984. DOI:10.1021/ES001526M
Lazarin A.M., Airoldi C. (2007). Thermochemistry of intercalation of n alkylmonoamines into lamellar hydrated barium phenylarsonate, Thermochimica Acta, 454(1), 43-49.
https://doi.org/10.1016/j.tca.2006.12.016. 13. Luo X., Wu C., Lin Y., Li W., Deng M., Tan J., Xue S. (2023), Soil heavy metal pollution from Pb/Zn smelting regions in China and the remediation potential of biomineralization. J Environ Sci (China). 125, 662-677. DOI: 10.1016/j.jes.2022.01.029. 14. Qu R., Niu Y., Liu J., Sun C., Zhang Y., Chen H., Ji C. (2008). Adsorption and desorption behaviors of Pd(II) on silica-gel functionalized with ester- and amino terminated dendrimer-like polyamidoamine polymers, React. Funct. Polym. 68, 1272. https://doi.org/10.1016/j.reactfunctpolym. 2008.06.005
Sales J.A.A, Petrucelli G.C., Oliveira F.J.V.E., Airoldi C. (2006). Some features associated with organosilane groups grafted by the
sol–gel process onto synthetic talc-like phyllosilicate, J. Colloid and Int. Science, 297(1), 95–103.
https://doi.org/10.1016/j.jcis.2005.10.019 16. Samal S., Mohapatra N.K., Acharya S., Dey R.K. (1999) Chelating resins VII: studies on chelating resins of formaldehyde and furfuraldehyde-condensed phenolic Schiff base derived from 4,4′- diaminodiphenylsulphone and o hydroxyacetophenone, Reactive and Functional Polymers, 42(1), 37-52. https://doi.org/10.1016/S1381-
(98)00055-8
Sprynskyy M., Buszewski B, Terzyk A.P., Namieśnik J. (2006). Study of the selection mechanism of heavy metal (Pb2+, Cu2+, Ni2+, and Cd2+) adsorption on clinoptilolite, Journal of Colloid and Interface Science, 304(1), 21-28, https://doi.org/10.1016/j.jcis.2006.07.068.
Tsubokawal N. (2007). Surface grafting of polymers onto nanoparticles in a solvent free dry-system and applications of polymer-grafted nanoparticles as novel functional hybrid materials, Polym. J., 39, 983.
https://doi.org/10.1295/polymj.PJ2007035 19. Zhang Y., Qu R., Sun C., Chen H., Wang C., Ji C., Yin P., Sun Y., Zhang H., Niu Y., (2009). Comparison of synthesis of chelating resin silica-gel-supported diethylenetriamine and its removal properties for transition metal ions, Journal of Hazardous Materials, 163 (1), 127-135., https://doi.org/10.1016/j.jhazmat.2008.06.0 70
