Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K

Authors

  • Atri D Tripathi Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • NiKhil Rajput Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Prakhar Kumar Dev Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.
  • Arshan Ahmad Dept. of Chemistry, Faculty of Engineering, Teerthanker Mahaveer University, Moradabad, Uttar Pradesh 244001, India.

DOI:

https://doi.org/10.48165/bpas.2023.42C.1.4%20

Keywords:

Excess Volume, Acetylene Tetrachloride, Pyridine, Methoxybenzene

Abstract

A dilatometric measurement have been carried out for getting excess volumes, VE, in the liquid state for  mixtures of acetylene tetrachloride (CHCl2CHCl2), with pyridine (C5H5N), methoxybenzene (C6H5O  CH3), 2-butanone (CH3COC2H5) and 1,4-dioxane (1,4-C4H8O2) at 298.15K and under atmospheric  pressure. The values of excess molar volume, VE, are negative in sign for all the mixtures over whole  composition range. Obtained data have been fitted by Redlich-Kister type polynomial smoothing  equation. The results are discussed in the light of molecular interactions occurred between components in  the liquid state. 

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References

Jagan Nath and A.D. Tripathi, (1983). Binary systems of 1,1,2,2-tetrachloroethane with benzene, toluene, p-xylene , acetone and cyclohexane. Part 1. Excess volumes and adiabatic compressibilities at 303.15 and 308.15K. J. Chem. Eng. Data, 28, 263-266.

Jagan Nath and A.D. Tripathi, (1984). Binary systems of 1,1,2,2-tetrachloroethane with

benzene, toluene, p-xylene , acetone and cyclohexane. Part 2. Dielectric Properties at 308.15 K. J. Chem. Soc. Farad. Trans. 1, 80, 1517-1524.

Tripathi AD, Singh VK, Purohit M, Bisht K, Rajput M. (2021). Excess Molar Volumes of Binary Liquid Mixtures of Ketocyclohexane (C6H10O), +CH2Cl2, +CHCl3, +CH2ClCH2Cl, +CHClCCl2, and +CCl 3CH3 at 303.15 K. Bull. of Pure & Appl. Sci. 40C(1), 1-6.

Riddick, J. A.; Bunger, W.B. (1970). Techniques of Chemistry, Organic Solvents: Physical Properties and Methods of Purification, 3rd ed.; Wiley-Interscience: New York, 1970.

Published

2023-06-20

How to Cite

Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K . (2023). Bulletin of Pure and Applied Sciences-Chemistry , 42(1), 22–26. https://doi.org/10.48165/bpas.2023.42C.1.4