Excess Volume for Acetylene Tetrachloride with Pyridine, Methoxybenzene, 2-Butanone and 1,4-Dioxane at 298.15K
DOI:
https://doi.org/10.48165/bpas.2023.42C.1.4%20Keywords:
Excess Volume, Acetylene Tetrachloride, Pyridine, MethoxybenzeneAbstract
A dilatometric measurement have been carried out for getting excess volumes, VE, in the liquid state for mixtures of acetylene tetrachloride (CHCl2CHCl2), with pyridine (C5H5N), methoxybenzene (C6H5O CH3), 2-butanone (CH3COC2H5) and 1,4-dioxane (1,4-C4H8O2) at 298.15K and under atmospheric pressure. The values of excess molar volume, VE, are negative in sign for all the mixtures over whole composition range. Obtained data have been fitted by Redlich-Kister type polynomial smoothing equation. The results are discussed in the light of molecular interactions occurred between components in the liquid state.
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References
Jagan Nath and A.D. Tripathi, (1983). Binary systems of 1,1,2,2-tetrachloroethane with benzene, toluene, p-xylene , acetone and cyclohexane. Part 1. Excess volumes and adiabatic compressibilities at 303.15 and 308.15K. J. Chem. Eng. Data, 28, 263-266.
Jagan Nath and A.D. Tripathi, (1984). Binary systems of 1,1,2,2-tetrachloroethane with
benzene, toluene, p-xylene , acetone and cyclohexane. Part 2. Dielectric Properties at 308.15 K. J. Chem. Soc. Farad. Trans. 1, 80, 1517-1524.
Tripathi AD, Singh VK, Purohit M, Bisht K, Rajput M. (2021). Excess Molar Volumes of Binary Liquid Mixtures of Ketocyclohexane (C6H10O), +CH2Cl2, +CHCl3, +CH2ClCH2Cl, +CHClCCl2, and +CCl 3CH3 at 303.15 K. Bull. of Pure & Appl. Sci. 40C(1), 1-6.
Riddick, J. A.; Bunger, W.B. (1970). Techniques of Chemistry, Organic Solvents: Physical Properties and Methods of Purification, 3rd ed.; Wiley-Interscience: New York, 1970.