Fabrication Of Dye-Sensitized Solar Cells Using Aqueous And Ethanolic Extracts Of Ixora Macrothyrsa Flowers
DOI:
https://doi.org/10.48165/Keywords:
FTO, photovoltaics, Ixora, solvothermal, TiO2Abstract
Dye-sensitized solar cells (DSSCs) are promising types of photovoltaic cells which have the capability to generate electrical energy at low fabrication cost in comparison to the silicon crystalline solar cells. Titanium dioxide (TiO2) nanoparticles were synthesized by solvothermal method. DSSCs using Ixora macrothyrsa flowers as dye-sensitizer were fabricated using l as solvents. The structural and surface properties of TiO2 nanoparticles were characterized using X-ray diffraction and Field Emission Scanning Electron Microscopy. The synthesized TiO2 material had tetragonal crystal structure which was highly stable and crystalline. The extracted natural dyes were characterized by UV-visible absorption pectroscopy and Fourier transform infrared (FTIR). The bandgap energy of TiO2 photoanode was studied by using UV-visible spectra and the y using FTIR spectra. The photo-electrochemical parameters and efficiency of DSSC were measured using-measurement system. The result of J-V characteristics showed that the efficiency of DSSC’s based on TiO2 nanoparticles extracted from Ixora flowers using ethanol solvent was better than water solvent.
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Almahy, H.A., Ali, M.A. and Band, A. 2013. Extraction of carotenoids as natural dyes from Daucus carota Linn (carrot) using ulturasound in Kingdom of Saudi Arabia. Research Journal of Chemical Sciences, 3(1): 63-66.
Arora, A.K., Devi, S., Jaswal, V.S., Singh, J., Kinger, M. and Gupta, V.D. 2014. Synthesis and characterization of ZnO nanoparticles. Oriental Journal of Chemistry, 30(4): 1671-1679. Atli, A., Atilgan, A., Altinkaya, C., Ozel, K. and Yildiz, A. 2019. St. Lucie cherry, yellow jasmine, and madder berries as novel natural sensitizers for dye‐sensitized solar cells. International Journal of Energy Research, 43(8): 3914-3922.
Calogero, G., Yum, J.H., Sinopoli, A., Di Marco, G., Grätzel, M. and Nazeeruddin, M.K. 2012. Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells. Solar Energy, 86(5): 1563-1575.
Caramori, S., Cristino, V., Boaretto, R., Argazzi, R., Bignozzi, C.A. and Di Carlo, A. 2010. New components for dye-sensitized solar cells. International Journal of Photoenergy, 2010: Article ID 458614 [doi:10.1155/2010/458614].
E. Selva Esakki et al.
Esakki, E.S., Sarathi, R., Sundar, S.M. and Devi, L.R. 2021. Fabrication of dye sensitized solar cells using Ixora macrothyrsa. Materials Today: Proceedings, 9: 2182-2187.
Fukai, Y., Kondo, Y., Mori, S. and Suzuki, E. 2007. Highly efficient dye-sensitized SnO2 solar cells having sufficient electron diffusion length. Electrochemistry Communications, 9: 1439-1443. Guruvammal, D., Selvaraj, S. and Sundar, S.M. 2016. Effect of Ni-doping on the structural, optical and magnetic properties of ZnO nanoparticles by solvothermal method. Journal of Alloys and Compounds, 682: 850-855.
Harborne, J.B. and Williams, C.A. 2000. Advances in flavonoid research since 1992. Phyto chemistry, 55(6): 481-504.
O'Regan, B. and Grätzel, B. 1991. A low-cost, high-efficiency solar cell based on dye sensitized colloidal TiO2 films. Nature, 353: 737-739.
Sanjay, P., Isaivani, I., Deepa, K., Madhavan, J. and Senthil, S. 2019. The preparation of dye sensitized solar cells using natural dyes extracted from Phytolacca icosandra and Phyllanthus reticulatus with ZnO as photoanode. Materials Letters, 244: 142-146.
Sayama, K., Sugihara, H. and Arakawa, H. 1998. Photoelectrochemical properties of a porous Nb2O5 electrode sensitized by a ruthenium dye. Chemical Materials, 10: 3825-3832. Shalini, S., Prasanna, S., Mallick, T.K. and Senthilarasu, S. 2015. Review on natural dye sensitized solar cells: Operation, materials and methods. Renewable and Sustainable Energy Reviews, 51: 1306-1325.
Sowmya, S., Prakash, P., Ruba, N., Janarthanan, B., Nagamani Prabu, A. and Chandrasekaran, J. 2020. A study on the fabrication and characterization of dye-sensitized solar cells with Amaranthus red and Lawsonia inermis as sensitizers with maximum absorption of visible light. Journal of Materials Science: Materials in Electronics, 31(8): 6027-6035.
Trihutomo, P., Soeparman, S., Widhiyanuriyawan, D. and Yuliati, L. 2019. Performance improve ment of dye-sensitized solar cell-(DSSC-)-based natural dyes by clathrin protein. International Journal of Photoenergy, 2019: Article ID 4384728 [https://doi.org/10.1155/2019/4384728].
Varadhaseshan, R. and Sundar, S.M. 2012. Existence of ferromagnetism and structural character ization of nickel doped ZnO nanocrystals. Applied Surface Science, 258(18): 7161-7165. Vasanthapriya, R., Neelakandeswari, N., Rajasekaran, N., Uthayarani, K. and Chitra, M. 2018. Synthesis and characterization of SnO2 nanostructures for dye-sensitized solar cells. Materials Letters, 220: 218-221.
Wang, X.F., Matsuda, A., Koyama, Y., Nagae, H., Sasaki, S.I., Tamiaki, H. and Wada, Y. 2006. Effects of plant carotenoid spacers on the performance of a dye-sensitized solar cell using a chlorophyll derivative: Enhancement of photocurrent determined by one electron-oxidation potential of each carotenoid. Chemical Physics Letters, 423(4-6): 470-475.
Wang, Y.X., Shen, Z.C., Huang, D.D. and Yang, Z.S. 2018. High-performance ZnO nanosheets/ nanocrystalline aggregates composite photoanode film in dye-sensitized solar cells. Materials Letters, 214: 90-99.